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Most Valuable Iron Man Villains Comics

Iron Man Villains: First Appearance Comic Book Values

Origin and first appearance stories are the key to the most expensive comic books. The first time a hero or villain is published is a big deal.

Iron Man Villains: The Crimson DynamoIron Man Villains: The Crimson Dynamo

Collectors seek these origin stories and first appearances keenly. This demand drives up prices.

Iron Man antagonists are not immune to this phenomenon. And that's great news if you happen to find them in your collection!

Most of the key issues on this page are from Tales of Suspense comics. They feature not only the first Iron Man appearances, but many of the bad guys too.

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Value of First Appearance Comics with Iron Man Villains

  • Advanced Idea Mechanics
  • Arsenal
  • Blizzard
  • Black Knight
  • Blood Brothers
  • Boomerang
  • Count Nefaria
  • Crimson Dynamo
  • Dreadnought
  • Fin Fang Foom
  • Ghost
  • Gladiator
  • Grey Gargoyle
  • Guardsman
  • HYDRA
  • Jack Frost
  • Justin Hammer
  • Korvac
  • Living Laser
  • Madame Masque
  • Mandarin
  • Melter
  • MODOK
  • Spymaster
  • Super-Adaptoid
  • Thanos
  • Titanium Man
  • Unicorn
  • Ultron
  • White Dragon
  • Whiplash

Strange Tales #146
1st Advanced Idea Mechanics (A.I.M.)

Lowest price $10

Average price $132

Record price $1,700

A.I.M. is a branch of HYDRA dedicated to the use of technology to achieve world domination. Think Tesla meets Meta...

Iron Man #114
1st Arsenal

Lowest price $1

Average price $40

Record price $180

Arsenal was a giant fighting robot. Created by Howard Stark to be used in last resort during WWII, it was stored, but was activated and attacked the Avengers.

Iron Man #86
1st Blizzard

Lowest price $5

Average price $60

Record price $315

Blizzard is a spin-off from the original cold-generating battle suit created by Jack Frost in Tales of Suspense #45. (See below.)

Avengers #48
First Silver Age Black Knight

Lowest price $40

Average price $200

Record price $10,600

Dane Whitman is the Silver Age Black Knight, part of the MCU.

Iron Man #55
First Blood Brothers and Thanos

Lowest price $100

Average price $500

Recent 9.8 Sale $8,000

Record price $19,000

Thanos famously snapped his fingers and made half the universe die in the Endgame saga.

Blood Brothers also debut here. They are ape-like aliens who serve Thanos.

Tales to Astonish #81
1st Boomerang

Lowest price $10

Average price $70

Record price $445

Boomerang was a disgraced major league baseball pitcher.

Recruited by the Secret Empire, he committed crimes by... drum roll... throwing boomerangs.

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Avengers #13
1st Count Nefaria

Lowest price $25

Average price $140

Record price $8,300

Count Nefaria is a long-running criminal who masterminds crimes against various Marvel heroes, including Captain America, the X-Men and the Avengers.

Tales of Suspense #46
1st Crimson Dynamo

Lowest price $30

Average price $250

Record price $12,700

Crimson Dynamo is a B-list Iron Man villain whose race was pretty much run by the Bronze Age of comics.

Strange Tales #154
1st Dreadnought

Lowest price $5

Average price $100

Record price $1,000

Created by HYDRA, Dreadnought is a non-sentient robot for use in commando operations.

Strange Tales #89
1st Fin Fang Foom

Lowest price $250

Average price $1,200

Record price $18,600

Fin Fang Foom was an alien monster in deep slumber. Reawakened by a Chinese scholar, it wreaked havoc on the world.

Iron Man #219
1st Ghost

Lowest price $1

Average price $40

Record price $700

The antagonist in the MCU movie Ant-Man and the Wasp, Ghost has the ability to pass through walls or turn invisible.

Daredevil #18
1st Gladiator

Lowest price $20

Average price $150

Record price $10,800

Gladiator was the handiwork of a deluded costume designer, who believed he was better than superheroes.

Journey into Mystery #107
1st Grey Gargoyle

Lowest price $35

Average price $200

Record price $4,300

Grey Gargoyle was a chemist. He invented a compound which allowed him to turn objects he touched to stone.

Iron Man #31
1st Guardsman

Lowest price $10

Average price $65

Record price $925

Guardsman was Kevin O'Brien, a former friend and colleague of Tony Stark. His brain was affected by a malfunction in his super-suit, and he turned evil.

Strange Tales #135
1st HYDRA; 1st Nick Fury, Agent of S.H.I.E.L.D.

Lowest price $65

Average price $350

Record price $20,400

HYDRA is a criminal network bent on world domination.

It is a long-time source of some of the worst threats to humanity, and the backdrop to many of the MCU properties.

Tales of Suspense #45
1st Pepper Potts and Happy Hogan;
1st Jack Frost

Lowest price $150

Average price $700

Record price $24,000

Love interest Pepper Potts (played in the MCU by Gwyneth Paltroe) appears for the first time in this issue. Also Happy Hogan, who you may recall from cameos in various MCU properties.

Jack Frost was the nickname for the villain Gregor Shapanka. His cold-generating battle suit helped him to commit crimes.

Iron Man #120
1st Justin Hammer

Lowest price $1

Average price $45

Record price $555

Justin Hammer is a multi-billionaire criminal who, amongst other acts, pays to bail out costumed criminals from jail.

Giant-Size Defenders #3
1st Korvac

Lowest price $5

Average price $50

Record price $1,500

Michael Korvac was a traitor to humanity whose body was fused to a robot, making him effectively a cyborg.

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Avengers #34
1st Living Laser

Lowest price $10

Average price $80

Record price $3,000

The Living Laser was Arthur Parks, who designed laser projectors for his wrists. He developed an infatuation for the Wasp and kidnapped her.

Iron Man #17
1st Madame Masque

Lowest price $15

Average price $70

Record price $620

Madame Masque is the daughter of Count Nefaria. She wears a gold mask to cover her disfigured face.

Tales of Suspense #50
1st Mandarin

Lowest price $80

Average price $600

Record price $15,000

Mandarin has appeared twice in the MCU, once as an imposter in an Iron Man movie, the other as the antagonist to Shang-Chi.

Tales of Suspense #47
1st Melter

Lowest price $50

Average price $300

Record price $9,500

This is the last appearance of the gold Iron Man armor, and the first appearance of the Melter.

Tales of Suspense #94
1st MODOK

Lowest price $15

Average price $100

Record price $12,600

MODOK is a mutagenics creation, designed originally to do good, who takes over A.I.M. after becoming evil. He debuted in the MCU in Ant-Man and the Wasp: Quantumania.

Iron Man #33
1st Spymaster

Lowest price $10

Average price $50

Record price $450

Spymaster was originally a master of espionage, who was hired by Zodiac to infiltrate Stark Enterprises.

There were several Spymasters over the years, and he became one of the most long-running Iron Man villains.

Tales of Suspense #84
1st Super-Adaptoid

Lowest price $20

Average price $100

Record price $3,700

Super-Adaptoid was an android containing a shard of the Cosmic Cube. It was designed to destroy Captain America.

Tales of Suspense #69
1st Titanium Man

Lowest price $15

Average price $100

Record price $1,900

Titanium Man was a member of the KGB. He recruited the creator of Crimson Dynamo to create a suit of titanium armor.

Tales of Suspense #56
1st Unicorn

Lowest price $25

Average price $100

Record price $2,880

Unicorn was created by the Crimson Dynamo, who built him armor. He later allied with Count Nefaria.

Avengers #55
First Ultron

Lowest price $30

Average price $150

Record price $2,300

Ultron, the alien invaders at the end of Age of Ultron, are a stark warning about the dangers of AI.

Iron Man #39
1st White Dragon

Lowest price $5

Average price $40

Record price $450

White Dragon attempted to reprogram Tony Stark's mind to get him to undermine the United Nations.

Tales of Suspense #97
1st Whiplash

Lowest price $5

Average price $80

Record price $980

Whiplash is a rogue employee of Stark Enterprises. He became an Iron Man villain, wielding a special whip of his own design.

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Comics and Collectibles Near ME is buying Iron Man Villains comics!